(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007).

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2020-09-16T09:38:03+02:00 Ambient Moisture Accelerates Hydroamination Reactions of Vinylarenes with Alkali‐Metal Amides under Air. <> An improved method for tricyanovinilation of aromatic amines under ultrasound irradiation. Amines are common in fine-chemical, pharmaceutical, and agricultural industries.
Eine allgemeine rutheniumkatalysierte Synthese von aromatischen Aminen. Lithium‐Catalyzed anti‐Markovnikov Intermolecular Hydroamination Reactions of Vinylarenes and Simple Secondary Amines. Base‐Catalysed Intramolecular Hydroamination of Vinyl Sulfides.

endobj The reaction was performed in dioxane under a blue light-emitting diode (LED) at room temperature. Such materials are peer reviewed and may be re‐organized for online delivery, but are not copy‐edited or typeset.

As a service to our authors and readers, this journal provides supporting information supplied by the authors.

<. Intermolecular hydroaminations of unactivated alkenes, however, can be challenging. A ruthenium-catalyzed intermolecular, anti-Markovnikov hydroamination of vinylarenes with secondary aliphatic and benzylic amines is reported.

In addition, existing methods for this type of reaction usually give the Markovnikov products (which are aminated at the higher-substituted carbon). N -Alkyl Amine Synthesis by Hydroamination of Alkene and Diene.

Department of Chemistry, University of Liverpool, Liverpool, L69 7ZD UK.

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Rare-earth metal diisopropylamide-catalyzed intramolecular hydroamination. endobj The reaction conditions are mild and effect a range of cyclization modes to give important nitrogen-containing heterocycles. v+��n�&m#iR�ԯ7�+���\��T�E���w��R��:�#��#P�h�SY�8Yy Ɇ ҁ�6�B{�u

Anti-Markovnikov Hydroamination of Alkenes with Aqueous Ammonia by Metal-Loaded Titanium Oxide Photocatalyst J. Nitrogen atoms are ubiquitous in pharmaceuticals, natural products, materials, and commodity chemicals. CH Bond Activation with Triel Metals: Indium and Gallium Zwitterions through Internal Hydride Abstraction in Rigid Salan Ligands. and you may need to create a new Wiley Online Library account. Author information: (1)Department of Chemistry, Yale University, P.O. These authors contributed equally to this work.

endobj Hydroamination is the addition of an N-H bond of an amine across a carbon-carbon multiple bond of an alkene, alkyne, diene, or allene.

Working off-campus? 15 0 obj Homogeneous Catalytic Hydroamination of Alkynes and Allenes with Ammonia. Please check your email for instructions on resetting your password.

Any queries (other than missing content) should be directed to the corresponding author for the article. Unexpected Rearrangement of Dilithiated Isoindoline-1,3-diols into 3-Aminoindan-1-ones

Consecutive Intermolecular Reductive Hydroamination: Cooperative Transition‐Metal and Chiral Brønsted Acid Catalysis.


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