The compound is slightly soluble in water and sometimes freely soluble in the chemicals such as alcohol and ether. Tax calculation will be finalised during checkout. /Root 64 0 R Treatment of aniline by catalytic wet air oxidation: Comparative study over CuO/CeO. 0000011500 00000 n The above image shows the structure of an Aniline compound.
It has a chemical formula of C6H5NH2 or C6H7N and since it has 6 carbon atoms, 1 nitrogen atom and 7 hydrogen atoms in its chemical formula, it is classified under organic compounds. LIANG Chen-ju, BRUELL C J, MARLEY M C, SPERRY K L. Persulfate oxidation for in situ remediation of TCE: II. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. << 68 0 obj 0000011073 00000 n Copyright © 2020 Elsevier B.V. or its licensors or contributors.
0000000015 00000 n Working off-campus?
118 0 R volume 21, pages1441–1447(2014)Cite this article. A novel advanced oxidation process to degrade organic pollutants in wastewater: Microwave-activated persulfate oxidation [J].
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LI Shen-xin, WEI Dong, MAK N K, CAI Zong-wei, XU Xiang-rong, LI Hua-bin, JIANG Yue.
Chemical Reviews 1994, 94 (6 ... Synergetic Effect of Ethylene Dibromide and Air as Oxidants.
If you are on a personal connection, like at home, you can run an anti-virus scan on your device to make sure it is not infected with malware. The aniline compounds are said to have the formula C6H5NH2 wherein the amino group is supposed to be attached to the Phenyl group. ScienceDirect ® is a registered trademark of Elsevier B.V. ScienceDirect ® is a registered trademark of Elsevier B.V. 0000001590 00000 n Here we report a novel method in which air ox-ygen is used as an oxidant for the polymerization of aniline in the presence of Cu(NO 3) 2 as a cata-lyst. Degradation of diphenylamine by persulfate: Performance optimization, kinetics and mechanism [J].
Accordingly, in the present study, novel luminescent organic nanorods (ONs) are synthesized through one‐step air oxidation of para ‐substituted anilines without any … Yong-qing Zhang 张永清. The results indicate that the concentration of chelating agent and ferrous ion didn’t follow a linear relationship with the degradation rate of aniline. As shown in this article, the catalytic process has been studied under various conditions, and the
The compound is soluble in water. The findings of this study provide a new strategy for the preparation of luminescent organic nanomaterials, and show their potential for optoelectronic applications. endobj
0000018564 00000 n << The catalytic effects of the prepared nanostructured catalysts, CuO/CeO2 (10% wt) and NiO/Al 2 O 3 (10% wt), on the CWAO treatment … endobj
Learn more about Institutional subscriptions. Thus N, N -diethylethanamine (triethylamine) can be oxidized to triethylazane oxide (triethylamine oxide): Basicity- As it is known that anilines are weak bases. /CropBox[0 0 630 810] Your IP: 176.9.39.183 Acylation- In acylation reaction, anilines reacts readily with carboxylic acids forming amides. XIE Xiao-fang, ZHANG Yong-qing, HUANG Wei-lin. Environmental science, 2008, 29(5): 1240–1243. /O 65 0000048866 00000 n https://doi.org/10.1007/s11771-014-2083-4. It is employed in the production of drugs such as paracetamol, Tylenol, acetaminophen.
Learn more. Tel. South Univ. Have you ever wondered what is behind the blue colour of the jeans you wear? 0000033110 00000 n
Addition, Reduction, and Oxidation Reactions of Nitrosobenzene. Addition, Reduction, and Oxidation Reactions of Nitrosobenzene. Chemosphere, 2009, 74(10): 1335–1339. 66 0 obj
These are used in a wide variety of industrial and are known to possess all the characteristics of an aromatic compound. 0000002119 00000 n These compounds are said to be toxic in nature and also known to be one of the classes of aromatic amines. College of Environment and Energy, South China University of Technology, Guangzhou, 510006, China, Yong-qing Zhang 张永清, Xiao-fang Xie 谢晓芳, Shao-bin Huang 黄少斌 & Hai-yun Liang 梁海云, Guangdong Provincial Key Laboratory of Atmospheric Environment and Pollution Control, Guangzhou, 510006, China, State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou, 510640, China, You can also search for this author in Influence of pH on persulfate oxidation of TCE at ambient temperatures [J]. 0000007271 00000 n KILLIAN P F, BRUELL C J, LIANG Chen-ju. Journal of Colloid and Interface Science, 1984, 98(2): 295–305. Accordingly, in the present study, novel luminescent organic nanorods (ONs) are synthesized through one‐step air oxidation of para‐substituted anilines without any shape‐guiding surfactants.
<> The treatment of aniline by catalytic wet air oxidation (CWAO) was studied in a bubble reactor. 0000019005 00000 n Cent. Performance & security by Cloudflare, Please complete the security check to access. TAN Chao-qun, GAO Nai-yun, CHU Wen-hai, LI Cong, MICHAEL R T. Degradation of diuron by persulfate activated with ferrous ion [J]. Aniline is an organic compound with the formula C 6 H 5 NH 2.Consisting of a phenyl group attached to an amino group, aniline is the simplest aromatic amine.Its main use is in the manufacture of precursors to polyurethane and other industrial chemicals. Application of potassium permanganate as an oxidant for in situ oxidation of trichloroethylene-contaminated groundwater: A laboratory and kinetics study [J]. It smells like the odour of a rotten fish.
Metallic salts. Look at the Carbon molecule, since its the central atom, we assign its oxidation number by following a set of rules based on the rest of the atoms. 0000011797 00000 n radical with Fe (II) in acidic aqueous solution-A pulse radiolysis study [J]. 15 The anilinium cation is the dominant species in strongly acidic medium (pH < 1), in which electrochemical oxidation of aniline is typically conducted (pKa of aniline is 4.6), while significant amount of more reactive neutral …
0 )/��Pdg�S�g*`��}����I��@��8����k�/�8�b��BX�0�Ӥs�F/�qYk4�v���ϐ�����Ɂ��"3�4;��t��H1�e,��ρ�(�e�;7��\f.�0� 2{� It is a kind of chemical substance which is a flammable liquid and has an unpleasant odour. Google Scholar. 0000030889 00000 n GUPTA S S, GUPTA Y K. Hydrogen ion dependence of the oxidation of iron (II) with peroxydisulfate in acid perchlorate solutions [J]. et al. +*A�G4�]J�Y�ae�Ԋ��ê��-��_������=��B�d2�"�O�H�]:m��(�m����
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15 Neutral aniline molecules are reported to be more easily oxidized than anilinium cations.
endobj Canadian Journal of Chemistry, 1974, 52(17): 3119–3124. /ColorSpace<>
Journal of Environmental Sciences, 2009, 21(9): 1175–1180. YANG Shi-ying, WANG Ping, YANG Xin, WEI Guang, ZHANG Wen-yi, SHAN Liang.
endobj https://doi.org/10.1016/j.jenvman.2012.08.036.
endobj Journal of Colloid and Interface Science, 2006, 300(2): 795–804. 0000033367 00000 n 0000053571 00000 n Degradation of diuron by persulfate oxidation activated by EDTA-ferrous ion in aqueous system [J].
Oxidation Reaction- The oxidation reactions of anilines compounds leads to the formation of carbon-nitrogen bonds.
Required fields are marked *. Use the link below to share a full-text version of this article with your friends and colleagues. XUE Xiao-fei, HANNA K, CHRISTELLE D, WU Feng, DENG Nan-sheng. <>stream
0000003682 00000 n
Journal of Chemical Technology & Biotechnology, 2013, 88(1): 145–152.
119 0 R LIANG Chen-ju, BRUELL C J, MARLEY M C, SPERRY K L. Persulfate oxidation for in situ remediation of TCE: I. ERDEMOGLU M, SARIKAYA M. Effects of heavy metals and oxalic acid on the zeta potential of magnetite [J].
TRAVINA O A, KOZLOV Y N, PURMAL A P, RODKO I Y. Synergism of the action of the sulfite oxidation initiators, iron and peroxydisulfate ions [J]. KOLTHOFF I M, MILLER I K. The chemistry of persulfate: I. HUANG Kun-chang, ZHAO Zhi-qiang, HOAG G E, DAHMANI A, BLOCK P A. Degradation of volatile organic compounds with thermally activated persulfate oxidation [J]. Journal of Contaminant Hydrology, 2009, 106(3/4): 173–182. /T 210493 ► Prepared catalysts seemed to be active having aniline removals around 45%.
0000002352 00000 n As shown in this article, the catalytic process has been studied under various conditions, and the On reaction with strong acids, the compounds form ions of anilinium.
BUXTON G V, MALONE T N, SALMON G A. Journal of the American Chemical Society, 1951, 73(7): 3055–3059. 120 0 R
LIANG Chen-ju, LIANG Ching-ping, CHEN Chi-chin. Chemosphere, 2007, 66(1): 106–113.
/Linearized 1.0 0000019507 00000 n
It is used as a dyeing agent in the manufacture of clothes such as jeans, etc. Metallic haircolors are also known as__. The full text of this article hosted at iucr.org is unavailable due to technical difficulties. /Resources 66 0 R It can also be colourless to light brown.
The prepared catalysts seem to be active having an aniline removal of 45.7% with CuO/CeO2 and 41.9% with NiO/Al2O3. - 196.41.123.183. 0000032406 00000 n ... Haircoloring products that change color gradually by progressive buildup and exposure to air contain__.
Aniline oxidation by hydrogen peroxide has been studied by Gontier and Tuel . ► Comparison of performances of nanostructured catalysts. 0000031673 00000 n 0000002576 00000 n endstream 0000032934 00000 n Journal of Electroanalytical Chemistry, 2007, 603(1): 44–50. 0000045606 00000 n
Accordingly, in the present study, novel luminescent organic nanorods (ONs) are synthesized through one‐step air oxidation of para ‐substituted anilines without any …
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